Introduction to Mineral Supplements
Minerals are inorganic compounds. Chemically, minerals are elements.
Dietary minerals are classified based on their concentration in the body
and dietary requirement. Macrominerals are minerals present at greater
than 100 ppm. In general, the concentration of macrominerals in the ration
is expressed as a percent of dry-matter. In general, the quantity of each
macromineral required per day is in the order of tenths of one gram (decigrams)
to one or more grams.
Table 10.1 lists the macrominerals and their abbreviations.
Table 10.1 - Macrominerals & Abbreviations
Macromineral |
Abbreviation |
Calcium |
Ca |
Chlorine |
Cl |
Magnesium |
Mg |
Phosphorus |
P |
Potassium |
K |
Sodium |
Na |
Sulfur |
S |
Microminerals, also referred to as trace minerals, are the minerals present
at less than 100 ppm. In general, the concentration of microminerals in
the ration is expressed as milligrams per kilogram. One ppm is equal to
one milligram per kilogram. In general, the quantity of each micromineral
required per day is on the order of millionths of a gram (micrograms)
to thousandths of a gram (milligrams).
Table 10.2 lists the microminerals and their abbreviations.
Table 10.2 - Microminerals & Abbreviations
Micromineral |
Abbreviation |
Chromium |
Cr |
Cobalt |
Co |
Copper |
Cu |
Fluorine |
F |
Iron |
Fe |
Iodine |
I |
Manganese |
Mn |
Molybdenum |
Mo |
Nickel |
Ni |
Selenium |
Se |
Silicon |
Si |
Zinc |
Zn |
Each of the macrominerals and microminerals is essential for supporting
maintenance and production functions; each mineral has at least one specific,
exclusive function.
Table 10.3 lists the primary functions of each of the macrominerals and
microminerals.
Table 10.3 -Function(s) of Macrominerals and Microminerals
Mineral |
Primary
Function(s) |
Calcium |
-Build and maintain bones and teeth
-Blood coagulation
-Muscle contraction and relaxation
-Nerve transmission
-Enzyme activation
-Secretion of hormones and hormone-releasing
factors
-Milk production and egg shell formation |
Chlorine |
-Regulation of osmotic pressure, water balance, and acid-base balance
-Production of HCl in gastric stomach |
Magnesium |
-Component of bones and teeth
-Cellular metabolism of ATP and ADP
-Protein digestion
-Relaxes nerve impulses
-Rumen buffer |
Phosphorus |
-Formation and maintenance of bones and teeth
-Milk secretion
-Building muscle tissue
-Component of nucleic acids
-Maintenance of osmotic and acid-base balance
-Metabolic functions associated with energy, phospholipids, amino
acids, and enzyme systems |
Potassium |
-Maintenance of acid-base balance
-Transfer of nutrients between cells
-Relaxes heart muscle
-Secretion of insulin
-Enzyme reactions
-Carbohydrate metabolism
-Protein synthesis |
Sodium |
-Maintenance of osmotic pressure and acid-base balance
-Component of secretions of the pancreas, liver, skin,
and other tissues
-Muscle contraction
-Nerve functions
-Carbohydrate metabolism |
Sulfur |
-Component of sulfur-containing amino acid, biotin,
thiamin, insulin, coenzyme A, certain complex carbohydrates and glutathione
-Detoxification
-Component of hair, wool, and feathers |
Chromium |
-Component of glucose tolerance factor
-Activator of enzymes in carbohydrate, protein, and fat metabolism
-Stabilize nucleic acids
-Synthesis of fatty acids and cholesterol |
Cobalt |
-Component of vitamin B-12 |
Copper |
-Metabolism of iron
-Formation of hemoglobin
-Several enzyme system
-Development and maintenance of vascular and
skeletal structures
-Central nervous system
-Pigmentation of hair and wool
-Component of proteins
-Reproduction |
Fluorine |
-Development of bones and teeth |
Iron |
-Component of hemoglobin and myoglobin
-Component of various enzymes
-Activator of enzymes |
Iodine |
-Production of iodine-containing hormones, thyroxin and triiodothyronine
involved in growth, nervous and muscle tissues, circulatory system,
and metabolism of all nutrients |
Manganese |
-Formation of bone
-Growth of connective tissues
-Blood clotting
-Insulin
-Cholesterol synthesis
-Activator of enzymes in carbohydrate, protein, lipid, and nucleic
acid metabolism |
Molybdenum |
-Component of enzyme systems in metabolism of carbohydrate, protein,
lipid, sulfur-containing amino acids, nucleic acids, and iron metabolism
Enzyme component in production of uric acid
-Growth-promoting effect
-Component of teeth |
Nickel |
-Enzyme function in protein and lipid metabolism |
Selenium |
-Component of enzyme which is an antioxidant
-Protection from specific toxic compounds |
Silicon |
-Growth and skeletal development |
Zinc |
-Skin, bones, hair, and feathers
-Component of enzyme systems involved in digestion and respiration
-Transfer of carbon dioxide in red blood cells
-Metabolism of proteins and nucleic acids
-Reproduction
-Immune function
-Function of insulin |
Total quantity of minerals in a feedstuff may be determined via the ash
procedure of proximate analysis; ash is an estimate of total mineral content
of a feedstuff. The quantity of individual mineral components requires
specialized analysis performed via a spectrophotometer. In addition to
quantity of a mineral, it is also important to consider quality (i.e.
bioavailability) of a mineral source. Bioavailability refers to the ability
of the mineral source to supply a digestible and absorbable form of the
mineral which may be subsequently utilized by the animal to support maintenance
and production functions.
Table 10.4 lists various mineral sources with intermediate and high relative
bioavailability.
Table 10.4 - Various Mineral Sources with Intermediate and High Bioavailability
Mineral |
Source |
Bioavailability |
Calcium |
Steamed bone meal
Monocalcium phosphate
Dicalcium phosphate
Defluorinated phosphate
Calcium carbonate
Ground limestone
Dolomite limestone |
High
High
High
Intermediate
Intermediate
Intermediate
Intermediate |
Phosphorus |
Calcium phosphate
Phosphoric acid
Sodium phosphate
Steamed bone meal
Defluorinated phosphate
Dicalcium phosphate |
High
High
High
High
Intermediate
Intermediate |
Magnesium |
Magnesium carbonate
Magnesium chloride
Magnesium oxide
Potassium and magnesium sulfate |
High
High
High
High |
Potassium |
Potassium chloride
Potassium sulfate
Potassium and magnesium sulfate |
High
High
High |
Sulfur |
Potassium sulfate
Potassium and magnesium sulfate
Sodium sulfate |
High
High
Intermediate |
Cobalt |
Cobalt carbonate
Copper sulfate |
High
High |
Copper |
Copper sulfate
Copper chloride
Copper carbonate
Copper nitrate |
High
High
Intermediate
Intermediate |
Iodine |
Potassium iodide, stabilized |
High |
Iron |
Ferrous sulfate |
High |
Manganese |
Manganese sulfate
Manganese carbonate |
High
High |
Selenium |
Sodium selenate
Sodium selenite |
High
High |
Zinc |
Zinc carbonate
Zinc sulfate
Zinc chloride |
High
High
Intermediate |
In addition to this table, the macrominerals sodium and chlorine are also
commonly supplemented. Sodium chloride, also known as salt, is the common
form of supplementation. As a result of the various factors, information
provided on bioavailability is an estimate versus a precise measure. Quantity
and quality of a mineral varies by mineral source and within a mineral
source.
In addition, the book values of mineral contents may not consistently
represent the actual mineral contents of a feedstuff. Therefore, it is
recommended to establish a schedule to analyze the mineral content of
feedstuffs. In general, the mineral contents of feedstuffs such as grains
will be relatively consistent. Generally, an estimate of ash content will
provide information regarding significant deviations from book values.
For significant deviations, it is recommended to perform an analysis for
individual minerals. As the mineral content may be variable in forages
and by-product feedstuffs, it is recommended to perform individual mineral
analyses on a more frequent schedule.
Table 8-1 on page 168-169 in the text lists sources of mineral supplements
utilized in feed supplements, complete feeds, or in mineralized salt.
The sources with an asterisk are sources most commonly utilized in commercial
feeds.
Mineral supplements may be classified as either natural or synthetic and
inorganic or organic. Inorganic sources do not contain carbon. Organic
sources do contain carbon. Generally, natural sources are minerals processed
to concentrate the mineral component and minimize the presence of contaminants.
Synthetic minerals are produced by chemical synthesis. Natural sources
may be either organic or inorganic. Synthetic sources may also be organic
or inorganic. One group of synthetic, organic minerals are chelated minerals.
Chemically, chelated minerals are composed of the mineral bound to an
organic compound. Chelated minerals are relatively expensive per unit
of mineral provided in the supplement. Research data do not conclusively
support chelated minerals based on the premise of improved utilization
of the mineral component. As an additional note, in general, mineral sources
in feedstuffs are in the organic form.
Mineral supplements may be added to the ration or offered ad-libitum.
In general, micronutrients require a carrier. As consumption of a supplement
offered ad-libitum varies by animal, it is recommended to add the mineral
and vitamin supplements to the complete feed at the appropriate rates
to promote adequate consumption of the supplement by each animal. Given
feeding situations may not allow addition of supplements to a complete
feed, various mineral and vitamin supplements in combination with salt,
to control consumption, may be offered ad-libitum.
In general, minerals provided in the various feedstuffs of the ration
and water do not fulfill the animal's dietary requirements for each mineral,
therefore additional supplementation of one or more of the minerals is
required. Selection of supplemental minerals is dependent upon cost per
unit of available mineral, absence of antinutritional factors, and physical
form. The specific mineral and quantity of each mineral to be supplemented
is influenced by factors such as animal species and physiological state,
available mineral content in the feedstuffs of the ration, and available
mineral content of the water source. Given the number of minerals, interrelationships
between the minerals, varied requirements for each of the minerals, and
varied ranges of subclinical and clinical toxicities for each of the minerals;
mineral supplementation is complex. Figure 8-1 on page 167 of the text
illustrates identified interactions between the various minerals.
As subclinical deficiencies and toxicities have the potential to impact
animal health and productivity, it is essential for a feed manager to
match mineral requirement to the mineral available to the best of their
ability. As a feed manager it is also important to realize commercial
mineral sources may not effectively meet the mineral requirements of the
animal. As evidenced by the data in Table 8-3 on page 175, mineral supplements,
even specialized formulations, may be deficient in or provide excess levels
of one or more minerals. In comparison to the potential impact on profitability,
the cost of mineral supplementation is minimal.
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