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Composition of Herbage

The chemical composition and subsequent nutritional value of a forage is complex and is influenced by a number of factors. The primary factors are plant species, environmental and soil conditions, and/or plant maturity. The following section will briefly discuss, in general terms, the chemical composition of forages.

The nitrogen component is expressed as crude protein content. Crude protein measures both protein and nonprotein nitrogen compounds in forages. Crude protein content is influenced by plant species, environmental and soil conditions, and stage of maturity. In general, the crude protein content of legumes is higher than the crude protein content of grasses. For legumes, in general, the range of crude protein is 15-30% on a dry-matter basis. For cool-season grasses, the content is lower at 10-20% on a dry-matter basis. For both legumes and grasses in specific situations, crude protein content can either be lower or higher than the given range. For grasses, crude protein content in the forage is dependent upon nitrogen fertilization. In general, the true protein accounts of 75-85% of the nitrogen. As the plant matures the portion of nitrogen as true protein increases. In excess of 200 NPN compounds have been identified across forages. Factors influencing the content of NPN compounds include environmental and soil conditions and plant species. Legumes contain higher contents of nonprotein amino acids compared to grasses. For nonruminants, the nutritional value of nonprotein amino acids is approximately half of the nutritional value of protein amino acids. In contrast, for ruminants, nonprotein amino acids are similar in nutritional value to amino acids present in protein molecules.

The next component is the carbohydrate component. The carbohydrate component may be divided into nonstructural or structural carbohydrates.


Nonstructural carbohydrates are the readily available carbohydrates in the forage. In forages, the concentrations of mono and disaccharides are relatively low; generally, less than 8% on a dry-matter basis. The primary mono and disaccharides in forages are glucose, fructose, and sucrose. The primary nonstructural polysaccharides in forages are starch and fructosans. Polysaccharides are the stored energy for the plant. In general, the primary nonstructural carbohydrates in legumes are sucrose and starch. For warm-season grasses, the primary nonstructural carbohydrate is starch. And for cool-season grasses, the primary nonstructural carbohydrate is fructosans. If harvested at similar stages of growth, total nonstructural carbohydrate content will be similar between cool-season legumes and grasses. The total nonstructural carbohydrate content varies by plant species, environmental conditions, and soil fertility. As a correction to the text, nonstructural carbohydrate content in forages is highest at the end of the day (i.e. following the photosynthetic daylight hours). Therefore, to increase the nonstructural carbohydrate content at harvest, forages are harvested following the daylight period.


The structural carbohydrates are comprised of polysaccharides. The three classes of structural carbohydrates in forages are pectic substances, noncellulosic polymers such as hemicellulose, and cellulose. Noncellulosic polymers and cellulose are digestible only by microbial enzymes. The structural carbohydrate content varies by species, and environmental conditions. As legumes mature, the most significant change in structural carbohydrates is the increase in stem cellulose. For grasses, with maturity, stem cellulose and hemicellulose increase.


The next chemical component of forages is lipids. In the leaf tissue, the lipid content ranges from 3-10%. The lipid content decreases with maturity. The majority of the lipids are galactolipids and phospholipids. Regarding fatty acids, 60-75% is linolenic acid. Upon disruption of the outer surface of the plant, unsaturated lipids are susceptible to oxidative processes.


The next component is organic acids. In general, the organic acid content of forages is not reported specifically on the analysis. In general, organic acid content is included with additional chemical components on an analysis. Organic acid content is included in the nitrogen-free extract portion of the proximate analysis and the cell contents or solubles portion of the detergent fiber system. Most of the organic acids in forages are nonvolatile. The organic acid content in forages ranges from 2-8% on a dry-matter basis. Organic acid content varies by plant species, maturity, and fertilization. Organic acids play a role in the palatability of a feedstuff.


Table 7-7 on page 126 of the text describes the range and typical mineral concentration for grasses and alfalfa. Note: the information on the table does not include all macro and microminerals provided in forages. Both grasses and legumes are high in potassium. In comparison to grasses, legumes contain a higher content of calcium, magnesium, sulfur, and copper. Grasses contain higher contents of manganese and zinc. Both grasses and legumes are moderate to low in phosphorus. The mineral content of forages is variable. Factors influencing the mineral content of forage include plant species and soil and environmental conditions.

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